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Safety Tips

 
CARBON DI-OXIDE
Source: Canadian Centre for Occupational Health and Safety


*** IDENTIFICATION *** RECORD NUMBER : 76402 LANGUAGE : ENGLISH PRODUCT NAME(S) : CARBON DIOXIDE (Gaseous) PRODUCT IDENTIFICATION DATA : PRODUCT NAME: Carbon Dioxide Gaseous DATE OF MSDS : 1985-07-18 *** MANUFACTURER INFORMATION *** MANUFACTURE : Liquid Carbonic Inc ADDRESS : 255 Brimley Road Scarborough Ontario Canada MIM 3J2 Telephone: 416-266-3161 EMERGENCY TELEPHONE NO.(S) : 613-996-6666(Canutec) 416-266-8600 (24 HOUR) DISCLAIMER: Note from Liquid Carbonic: The information contained in this Material Safety Data Sheet (MSDS) is provided by Liquid Carbonic Inc at no charge and has been compiled from published information believed to be reliable. Said information is only intended for use by skilled and knowledgeable people who are versed in the use of the specific product referred to herein to the exclusion of the use of such product in connection with any other product, material or process. Liquid Carbonic Inc assumes no responsibil ity for the inaccuracy of any data or statement contained herein or for events resulting from the use of the MSDS and shall not be liable for any direct, special, indirect or consequential damages in connection with the publication of the MSDS. No warranty, express or implied, of merchantability, fitness or otherwise is made. The MSDS is offered only for your consideration, investi gation and verification. *** MATERIAL SAFETY DATA *** TRADE NAME: CARBON DIOXIDE (Gaseous) SHIPPING NAME: Carbon Dioxide UN/PIN: 1013 TDG CLASSIFICATION: 2.2 MATERIAL SAFETY DATA SHEET PRODUCT NAME: Carbon Dioxide Gaseous SYNONYMS: Carbonic Acid Gas FORMULA: CO2 NATURE, APPEARANCE & ODOUR: Colourless, odourless(produces a sharp effect on nasal membrane sometimes described as punk odour) CHEMICAL COMPOSITION: Min.99.0% CO2 (vol/vol) --------------------------------------------------------------- PHYSICAL DATA BOILING POINT(at 1 atm) SPECIFIC GRAVITY NA sublimates at -78,5c (-109.3F) MELTING POINT NA PERCENT VOLATILE 100 VAPOUR PRESSURE @70F/21.1C) 838 EVAPORATION RATE @ 20 deg C NA psig VAPOUR DENSITY (AIR=1) @70F (21.1C) 1 ATM 1.522 SOLUBILITY (in water @ 20C vol/vol) 0.9 ---------------------------------------------------------------- FIRE EXPLOSION AND FIRE FIGHTING PHASES ----------------------------------------- FLASH POINT NA LOWER EXPLOSIVE LIMIT-- AUTO IGNITION TEMPERATURE- UPPER EXPLOSIVE LIMIT-- FIRE CLASS: Non flammable. Will not support combustion. NFPA RATING: EXPLOSION HAZARDS: Non flammable. Will not support combustion. Containers may rupt ure if subject to localized heat. HAZARDOUS PRODUCT OF COMBUSTION None EXTINGUISHING MEDIA: NA SPECIAL FIRE FIGHTING PROCEDURES: Use extinguishing media for surrounding fires. Keep cont ainers cool. ----------------------------------------------------------------- REACTIVITY DATA ----------------------------------------------------------------- PRODUCT: (at N.P.T.) Stable HAZARDOUS DECOMPOSITION: None INCOMPATIBILITIES: None HAZARDOUS DECOMPOSITION PRODUCTS: N/A CORROSITIVITY: In presence of moisture will from carbonic acid which corrode some metals.(Refer to specific Engineering Stand- ards on construction materials ----------------------------------------------------------------- ACUTE HEALTH THE HAZARD DATA ----------------------------------------------------------------- EYES: Non (contact with liquid or solid CO2 may cause (frostbite). SKIN: None (contact with liquid or solid CO2 may cause frostbite). INHALATION: S.T.E.L.(vol/vol)15,000 ppm (ACGIH 1984-85) INGESTION: None ----------------------------------------------------------------- CHRONIC HEALTH HAZARD DATA ----------------------------------------------------------------- EYES: None known SKIN: None known INHALATION: Concentrations above TLV may change blood pH TLV: 5,000 ppm (vol/vol) TWA (ACGIH 1984-85) --------------------------------------------------------------------- FIRST AID INFORMATION -------------------------------------------------------------------- EYES: Rinse with warm water for 15 minutes. Call physician. SKIN: Treat cases of frostbite.Call physician. INHALATION: Remove from contaminated area. Administer oxygen. Call physician. Keep patient warm and quiet. INGESTION: Ingestion of solid CO2 (dry ice) may cause severe burns on contact. Keep out of reach of children. -------------------------------------------------------------------- HEALTH/SAFETY/HANDLING PRECAUTIONS ---------------------------------------------------------------------- VENTILATION: Provide good ventilation. Maintain at least 18% oxygen concentration where CO2 is handled. HAND: Insulated gloves on non insulated piping systems. EYES AND FACE: Goggles. CLOTHING: -- RESPIRATORY EQUIPMENT:SCBA in case of suspected leak or oxygen deficient atmosphere. STORING AND HANDLING: Store containers away from sources of heat. Handle cylinders with cap when supplied. --------------------------------------------------------------- SPILL OR LEAK PROCEDURE ---------------------------------------------------------------- ACTION: Try to stop source of leak if without danger. Keep upwind. Do not walk on spilled material. Allow to evaporate to atmosphere. Keep unnec- cessary people away. Check concentration of CO2 before entering enclosed area of spill. NOTIFY: Nearest LCI plant. WASTE DISPOSAL: No residual waste METHOD: -- BIODEGRADABLE: Yes BIOACCUMULATOR No ISN: 76402 DATE OF ISSUE: July 18,1985

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